Honestly? I keep seeing this pairing pop up and I'm never quite sure where the appeal is supposed to be. Not that I'm against it, but the material from 'Big Hero 6: The Series' feels pretty thin for building a whole fic universe. Hiro's like 14 and Karmi's maybe a year older? The show gave them that academic rivalry-turned-mutual respect thing, which is a decent start, but there's a real lack of those charged, will-they-won't-they moments you need to fuel a ship. Most of the fics I've clicked on end up leaning hard on post-canon, aging them up scenarios which always feels like a workaround.
That said, if you're determined to dive in, your best bets are on Ao3 and FF.net obviously, but you gotta use specific tags. Just searching "Hiro/Karmi" gets you a mix. The ones that stand out tend to be the ones that fully commit to the sci-fi elements. I vaguely remember one called something like 'Peer Review' where they're rival inventors in a university setting, competing for grants but secretly collaborating on a project. It worked because it kept the core dynamic of intellectual one-upmanship while giving them adult agency. A lot of the others fall into the trap of making Karmi just a fangirl or Hiro just awkward, which loses the spark.
The other route the good ones take is crossover with other sci-fi properties. There was a weirdly popular one that mashed up the BH6 world with elements of 'Portal', with Karmi as a test subject and Hiro trying to break her out. That was more about puzzle-solving and tension than romance, but the pairing fit the scenario. I guess my take is that the top stories for this ship are the ones that aren't really about the ship at all, but use it as a component in a bigger, plot-driven machine. The pure fluff pieces rarely have enough to chew on.
You'll find a handful with decent kudos counts, but don't expect 'Evermore' or 'Violet Evergarden' levels of community engagement. It's a niche within a niche. Sort by kudos or bookmarks, skim the summaries for plots that sound substantive, and maybe check if the author has written other BH6 stuff successfully. Sometimes a writer who nails the team dynamics can make a rare pairing sing.