So I've spent way too much time digging for that specific flavor of Saiki brofic, the kind that really twists the knife. The go-to place is Archive of Our Own, obviously. Tag filtering is your friend – search for 'Saiki Kusuo/Kusuke' or the character tags individually, then add 'Angst,' 'Drama,' or 'Whump.' I find sorting by kudos on that pairing pulls up the heavy-hitters, stuff like 'Counterpoint' or 'The Observer Effect,' which have these fantastic, painful explorations of their screwed-up dynamic.
Sometimes the real dramatic gold is in the crossover tags, though. I stumbled on a wild one that fused their psychic rivalry into the 'Death Note' universe, which was... a lot. Tumblr blogs dedicated to the Saiki fam can also have links to shorter, punchier works on AO3 or even Quotev that might not have as many tags but nail the intense, twisted moments. Discord servers for the fandom often have fanfic rec channels; you gotta lurk a bit, but people there share hidden gems that don't always get mainstream traction.
It's tricky because 'dramatic twist' can mean a big reveal, a betrayal, or just the slow unraveling of their already fragile peace. I lean towards authors who treat Kusuke's obsession as a tragedy rather than just villainy, which tends to yield those layered, gut-punch narratives.